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noun, する verb
Remember how 直行 is "nonstop"? Well, with 直航 it's the same thing, but more like with flying things, making this a nonstop flight.
This is a jukugo word, which usually means on'yomi readings from the kanji. If you know the readings of your kanji you'll know how to read this as well.
This ship is on a direct voyage to Kobe Port.