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A fire wound is a burn or scald you got from fire (or other hot things). Ouch!
The reading for this is unlike anything you've seen with these kanji. Try to think about a burn (on your arm) being caused by a yakky dodo (やけど) bird (which is a dodo bird that has yak-like features). Take a look at how weird it is, and wonder why it is burning you. Feel the pain.
カレーを零して、手に火傷を負った。
I spilled curry and got a burn on my hand.
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